Odstranjevanje potencialno strupenih kovin iz odpadnega blata iz čistilne naprave z uporabo EDTA

Anela KAURIN, Juan Francisco MORALES ARTEAGA, Domen LEŠTAN

Povzetek


Odpadno blato iz čistilnih naprav (ČN) ima zaradi velike hranilne vrednosti potencial za uporabo v kmetijstvu, vendar je pogosto onesnaženo s potencialno strupenimi kovinami (PSK). V raziskavi smo preverili ali ReSoil® tehnologija, ki temelji na uporabi EDTA (50, 70 in 100 mmol l-1), omogoča učinkovito odstranjevanje PSK iz odpadnega blata, vzetega po aerobni (blato1) in anaerobni (blato2) biološki obdelavi. Največji delež odstranitve Pb smo dosegli v blatu1 (do 60 %), največji delež odstranitve Zn in Cu pa v blatu2 (do 55 in 29 %). Vsebnost hranil se po remediaciji ni bistveno spremenila, le vsebnost dostopnega fosforja se je v blatu2 po remediaciji do 1,7-krat zmanjšala, vendar je še vedno ostala velika (489-510 mg 100-1 g-1). Po remediaciji so bile koncentracije v izpirkih za vse kovine, razen za Zn, pod mejo za nenevarne snovi. Za dokazovanje možnosti recikliranja procesnih raztopin in EDTA smo blato2 oprali s 50 mmol l-1 pralno raztopino v seriji 5 zaporednih remediacij in pri tem v povprečju odstranili 28 % Pb, 48 % Zn, 35 % Cu, 30 % Mn in 10 % Fe. ReSoil® tehnologija sicer omogoča odstranjevanje PSK iz blata in pri tem ohrani njegovo hranilno vrednost, vendar je učinkovitost tehnologije odvisna od postopkov obdelave blata na ČN.


Ključne besede


EDTA; potencialno strupene kovine; remediacija; odpadno blato; čistilne naprave; aerobna biološka obdelava; anaerobna biološka obdelava

Celotno besedilo:

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Literatura


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DOI: http://dx.doi.org/10.14720/aas.2022.118.4.2705

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Avtorske pravice (c) 2022 Anela KAURIN, Juan Francisco MORALES ARTEAGA, Domen LESTAN

 

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